Self-assembly of natural and synthetic molecules yielding supramolecular structures of varied dimensions in the nano to micrometer range has been an area of increasing significance in recent years. These studies have helped scientists to improve the understanding of the structure property relationships … See more In conclusion, spontaneous formation of vesicular self-assemblies during an aerobic coupling reaction of two monomeric … See more DST Fast-Track (SR/FTP/CS-42/2001), SERB (EMR/2016/001123), Indo-Srilanka project (DST/INT/SL/P25/2016), UGC-SAP and DST-FIST, Vidyasagar University are gratefully acknowledged for providing financial support and … See more WebNov 4, 2013 · Self-assembly of racemic bis(4-pyridyl) ligands based on a 1,1′-binaphthyl scaffold leads to dinuclear metallosupramolecular rhombi. Whereas 6,6′-substituted derivatives do not show any self-sorting, giving rise to a statistical mixture of stereoisomers, their 3,3′-difunctionalised isomers self-sort in a preferred social self ...
Self-assembly of chiral BINOL cages via imine condensation
WebThe self-assembly of the compounds 2b–d in aprotic nonpolar liquids may have been driven by the intermolecular H-bonding from the CO–NH H … WebJul 19, 2024 · We present here the synthesis of chiral BINOL-derived (BINOL=1,1′-bi-2-naphthol) bisamine and bispyridine-aldehyde building blocks that can be used for the self-assembly of novel chiral Fe II 2 L 3 … how much is stamps
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WebSep 8, 2024 · The synthesis of unprecedented BINOL-derived cationic phosphonites is described. Through the use of these phosphanes as ancillary ligands in Au I catalysis, a highly regio- and enantioselective assembly of appropriately designed alkynes into 1-(aryl)benzo[5]carbohelicenes is achieved. The modular synthesis of these ligands and … WebTo nd out the effect of the longer alkyl chains in the self-assembly process, the decyloxy derivative 2c and dodecyloxy derivative 2d were also synthesized35 and the self-assembly properties of all the three derivatives 2b–2d were studied in Fig. 1 Aerial oxidation of b-naphthol units 1a –dyielding binol derivatives 2a . Path A: schematic ... WebHeterobimetallic asymmetric catalysts, such as the lanthanum–lithium–binaphthol … how much is stan per month australia